The origin of the boson peak and thermal conductivity plateau in low-temperature glasses.
نویسندگان
چکیده
We argue that the intrinsic glassy degrees of freedom in amorphous solids giving rise to the thermal conductivity plateau and the "boson peak" in the heat capacity at moderately low temperatures are directly connected to those motions giving rise to the two-level-like excitations seen at still lower temperatures. These degrees of freedom can be thought of as strongly anharmonic transitions between the local minima of the glassy energy landscape that are accompanied by ripplon-like domain wall motions of the glassy mosaic structure predicted to occur at T(g) by the random first-order transition theory. The energy spectrum of the vibrations of the mosaic depends on the glass transition temperature, the Debye frequency, and the molecular length scale. The resulting spectrum reproduces the experimental low-temperature boson peak. The "nonuniversality" of the thermal conductivity plateau depends on k(B)T(g)omega(D) and arises from calculable interactions with the phonons.
منابع مشابه
Hysteresis of Low-Temperature Thermal Conductivity and Boson Peak in Glassy (g) As2S3: Nanocluster Contribution
Experimental results of the thermal conductivity (k(T)) of nanostructured g-As2S3 during cooling and heating processes within the temperature range from 2.5 to 100 K have been analysed. The paper has considered thermal conductivity is weakly temperature k(T) dependent from 2.5 to 100 K showing a plateau in region from 3.6 to 10.7 K during both cooling and heating regimes. This paper is the firs...
متن کاملElectrical conductivity anomaly in silver vadadium-tellurite glasses at temperatures higher than a characteristic temperature: evidence for an ionic-nonadiabatic polaronic mixed conduction
Electrical conduction anomaly was observed in the mixed ion-polaron regime for xAg2O-40TeO2-(60-x)V2O5 glassy system with 0 ≤x≤ 50 mol%, which were prepared by common melt quenching method. For the understudied glasses, the temperature dependence of dc electrical conductivity was measured from a characteristic temperature to 380 K, which certified their semiconducting nature. The measured condu...
متن کاملOptimization of thermal curing cycle for a large epoxy model
Heat generation in an exothermic reaction during the curing process and low thermal conductivity of the epoxy resin produces high peak temperature and temperature gradients which result in internal and residual stresses, especially in large epoxy samples. In this paper, an optimization algorithm was developed and applied to predict the thermal cure cycle to minimize the temperature peak and the...
متن کاملMicrostructure, mechanical and thermal properties of chalcogenide glasses and glass-ceramics based on Se-As-Ge system nucleated by Sn
In particular, chalcogenide glasses and glass-ceramics are new materials that exhibit good transparency in infrared region (0.8-12µm). We can overcome the main weakness of these glasses by improving the hardness through controlling crystallization. In this paper, we report results of a study on chalcogenide glasses in the ternary system of As-Se-Ge with nominal composition of Snx (Se...
متن کاملThe crossover from propagating to strongly scattered acoustic modes of glasses observed in densified silica
Spectroscopic results on low frequency excitations of densified silica are presented and related to characteristic thermal properties of glasses. The end of the longitudinal acoustic branch is marked by a rapid increase of the Brillouin linewidth with the scattering vector. This rapid growth saturates at a crossover frequency Ω co which nearly coincides with the center of the boson peak. The la...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Proceedings of the National Academy of Sciences of the United States of America
دوره 100 4 شماره
صفحات -
تاریخ انتشار 2003